As an example, the moisture content of a concrete mixture with 334 kg/m3 (564 lb/yd3) of cement and a w/c of 0.45 and in a service environment with a 50% relative humidity could be estimated as follows:
Total water content:
334 kg cement/m3 times 0.45 w/c ~ 150 kg water/m3
(564 lb cement/yd3 times 0.45 w/c ~ 254 lb water/yd3 )Chemically bound water at 0.24 w/c:
334 kg cement/m3 times 0.24 w/c ~ 80 kg water/m3
(564 lb cement/yd3 times 0.24 ~ 135 lb water/yd3 )Moisture content:
150 kg water/m3 - 80 kg water/m3times .50 relative humidity ~ 35 kg water/m3
(254 lb water/yd3 – 135 lb water/yd3 times .50 relative humidity ~ 60 lb water/yd3)
In reality the relative humidity of the concrete will only reach 50% at the near surface of the concrete and the moisture gradient with depth will increase toward 100% relative humidity so this method of estimation would typically overstate the quantity of moisture available to leave the concrete due to the initial mixing water in the mixture.
This is only an estimate of the moisture available to leave the concrete, but may help to give some perspective to the limited amount of water that the concrete can contribute when considering the drying time of hardened concrete.
References:
Kosmatka, Steven H., Kerkhoff, Beatrix, Panarese, William C., Design and Control of Concrete Mixtures, 14th Edition, 2002 (revised 2008), 372 pg.
Kanare, Howard M., Concrete Floors and Moisture, 2nd Edition, 2008, 172 pg.
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